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National Repository of Grey Literature

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	The use of composite graphite electrode for voltammetric determination of phenylglyoxylic acid Šenholdová, Z. ; Navrátil, Tomáš ; Shanmugam, K. ; Barek, J. ; Žák, J. A composite electrode prepared from graphite powder and epoxy resin was applied as a working electrode for the determination of phenylglyoxylic acid (one of the metabolites of styrene) in human urine. Cathodic differential pulse stripping voltammetry was used and optimum conditions have been found giving the limit of determination about 5 mg L-1. All results were compared with those obtained using hanging mercury drop electrode. For the confirmation of suggested mechanism of the electrochemical reaction the elimination voltammetry with linear scan was used. Detailed record
	Voltammetric determination of genotoxic compounds using solid amalgam electrodes Barek, J. ; Čížek, K. ; Fischer, J. ; Navrátil, Tomáš ; Josypčuk, Bohdan Possibilities of voltammetric determinations of genotoxic organic compounds for environmental purposes were studied. Traditional mercury electrode was replaced by solid amalgam electrodes. It is possible to conclude that the obtained results are comparable with those, obtained on other types of electrodes. Detailed record
	Voltametrické stanovení kyseliny Thiodiglykolové v moči osob exponovaných i neexponovaných Šenholdová-Dlasková, Z. ; Navrátil, Tomáš ; Heyrovský, Michael Detailed record
	Recyclation and Transformation of Homocysteine as a Part of Detoxication Processes in the Cell Přistoupilová, K. ; Přistoupil, T. ; Šenholdová, Z. ; Navrátil, Tomáš ; Heyrovský, Michael The presented metabolic pathways explain how the transformation of homocysteine affects the detoxication processes in the human cell. On the one hand homocysteine is recycled to methionine; on the other hand it is transformed to cysteine. Both pathways are connected by B12 vitamin. Their relation to the thiodiglycolic acid (TDGA), which represents a part of the detoxication processes, is demonstrated on the scheme. The changes in TDGA concentration in urine were found to depend on the changes in redox equilibria (of vitamin B12, folic acid, homocysteine). Key Words: Thiodiglycolic acid, TDGA, vitamin B12, folic acid, metabolic pathways, homocysteine, detoxication. Detailed record

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